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However, their photophys. National Academy of Sciences.
Using sacrificial bonds, we show how brittle, unfilled elastomers can be strongly reinforced in stiffness and toughness up to 4 megapascals and 9 kJ per square meter by introducing a variable proportion of isotropically prestretched chains that can break and dissipate energy before the material fails. Their single-molecule white light emission is realized by tuning the degree of crystallization. The DCM derivative 3 displays a broad absorption band between and nm in a mixture of hexane and chloroform 3: The repeated mechanochem. This was achieved by synthesizing an asym.
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Zip code. Nonetheless, these fundamental questions have been addressed in recent times by several research groups of vastly different expertise leading to a considerable progress in the field of org.
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Here we present a coumarin dimer CD mechanophore that, when embedded near the mid-chain of poly Me acrylate polymers, activates under pulsed massagge conditions to yield coumarin chain-end functional polymers.
ACS Appl. SCP shows high contrast, linearly tunable mechanochromism and bright white-light emission arising from a combination of traditional fluorescence and thermally activated delayed fluorescence TADF.
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- These bistable donor-acceptor MIMs undergo redox-activated switching between two Pórticos states.
- The 2 structures exhibit Erotic and yellow fluorescence, resp.
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- Moreover, white-light emission was obsd.